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The effects of nitrogen-enriched air, supplied by an air separation membrane, on NOx emissions from a 1.9-L turbocharged direct-injection diesel engine were investigated. To enrich combustion air with more nitrogen, prototype air separation membranes were installed between the after-cooler and intake manifold without any additional controls. The effects of nitrogen-enriched combustion air on NOx emissions were compared with and without exhaust gas recirculation (EGR). At sufficient boost pressures (>50 kPag), nitrogen-enriched air from the membrane provided intake oxygen levels that were similar to those of EGR. Compared with EGR, nitrogen-enriched air provided 10-15% NOx reductions during medium to high engine loads and speeds. At part loads, when turbocharger boost pressure was low, the air separation membrane was not effective in enriching air with nitrogen. As a result, NOx reduction was lower, but it was 15-25% better than when EGR was not used.

While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO2 emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. Our research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

Particulate and gaseous emissions from a Mitsubishi Legnum GDI™ wagon were measured for FTP-75, HWFET, SC03, and US06 cycles. The vehicle has a 1.8-L spark-ignition direct-injection engine. Such an engine is considered a potential alternative to the compression-ignition direct-injection engine for the PNGV program. Both engine-out and tailpipe emissions were measured. The fuels used were Phase-2 reformulated gasoline and Indolene. In addition to the emissions, exhaust oxygen content and exhaust-gas temperature at the converter inlet were measured. Results show that the particulate emissions are measurable and are significantly affected by the type of fuel used and the presence of an oxidation catalyst. Whether the vehicle can meet the PNGV goal of 0.01 g/mi for particulates depends on the type of fuel used. Both NMHC and NOx emissions exceed the PNGV goals of 0.125 g/mi and 0.2 g/mi, respectively. Meeting the NOx goal will be especially challenging.

This paper presents the results of Argonne National Laboratory's assessment of the fuel-cycle energy and emissions impacts of 13 combinations of fuels and propulsion systems that are potential candidates for light-duty vehicles with tripled fuel economy (3X vehicles). These vehicles are being developed by the Partnership for a New Generation of Vehicles (PNGV). Eleven fuels were considered: reformulated gasoline (RFG), reformulated diesel (RFD), methanol, ethanol, dimethyl ether, liquefied petroleum gas (LPG), compressed natural gas (CNG), liquefied natural gas (LNG), biodiesel, Fischer-Tropsch diesel and hydrogen. RFG, methanol, ethanol, LPG, CNG and LNG were assumed to be burned in spark-ignition, direct-injection (SIDI) engines. RFD, Fischer-Tropsch diesel, biodiesel and dimethyl ether were assumed to be burned in compression-ignition, direct-injection (CIDI) engines. Hydrogen, RFG and methanol were assumed to be used in fuel-cell vehicles.

Recent advances in fuel-cell technology and low-emission, direct-injection spark-ignition and diesel engines for vehicles could significantly change the transportation vehicle power plant landscape in the next decade or so. This paper is a scoping study that compares total fuel cycle options for providing power to personal transport vehicles. The key question asked is, “How much of the energy from the fuel feedstock is available for motive power?” Emissions of selected criteria pollutants and greenhouse gases are qualitatively discussed. This analysis illustrates the differences among options; it is not intended to be exhaustive. Cases considered are hydrogen fuel from methane and from iso-octane in generic proton-exchange membrane (PEM) fuel-cell vehicles, methane and iso-octane in spark-ignition (SI) engine vehicles, and diesel fuel (from methane or petroleum) in direct-injection (DI) diesel engine vehicles.

The development of a laboratory test for cavitation erosion corrosion of aluminum pumps with engine coolants is described. It is based on the standard ASTM D2809 test stand but incorporates the pump and cover from a Chrysler 5.9l (360 cu. in.) engine. Operating conditions are varied to simulate components taken from vehicle service. Light duty vehicle service results, obtained in the Colorado Rocky Mountains, for three types of coolant technology with the test pump are presented. Field results include large variations in cavitation protection. Included were two organic acid (OA) coolants, a traditional North American silicate and a European OA silicate hybrid. Comparisons are drawn with the standard ASTM D2809 test, additional components are presented and corrosion morphology discussed.

This paper evaluates the total lifecycle impacts for hauling freight long distances over land in the United States. The dominant modes of surface freight transport in the United States are large motor trucks (tractor-semitrailer combinations) and trains. These vehicles account for a significant portion of the transportation sector's petroleum usage and atmospheric emissions (among which nitrogen oxides and particulate matter are especially important). The objective of this paper is to evaluate the potential for reductions in energy use (in particular, petroleum use) and atmospheric emissions that result from freight transport, possibly as the result of research and development on improved technology or alternative fuels, such as Fischer-Tropsch diesel and natural gas, or from mode shifts in competitive markets. The impacts examined include energy use, both in toto and the petroleum fraction, and emissions of greenhouse gases and nitrogen oxides and particulate matter.

Their high fuel economy is making light-duty vehicles with spark-ignition direct-injection (SIDI) engines attractive. However, the implications for exhaust emissions and the effects of fuel quality on emissions are not clear for this type of engine. A Mitsubishi Legnum with a 1.8-L GDI™ engine was tested on federal test procedure (FTP) and highway fuel economy cycles. The results were compared with those for a production Dodge Neon vehicle with a 2.0-L port fuel-injection (PFI) engine. The Mitsubishi was tested with Indolene, Amoco Premium Ultimate, and a low-sulfur gasoline. The Neon was tested only with Indolene. Both engine-out and tailpipe emissions were measured. Second-by-second emissions and hydrocarbon speciation were also evaluated. The SIDI engine provided up to 24% better fuel economy than the PFI engine on the highway cycle. Tailpipe emissions of oxides of nitrogen (NOx) from the SIDI vehicle using low-sulfur fuel were 40% less than those when using Indolene.

Air can be enriched with oxygen and/or nitrogen by selective permeation through a nonporous polymer membrane; this concept offers numerous potential benefits for piston engines. The use of oxygen-enriched intake air can significantly reduce exhaust emissions (except NOx), improve power density, lessen ignition delay, and allow the use of lower-grade fuels. The use of nitrogen-enriched air as a diluent can lessen NOx emissions and may be considered an alternative to exhaust gas recirculation (EGR). Nitrogen-enriched air can also be used to generate a monatomic-nitrogen stream, with nonthermal plasma, to treat exhaust NOx. With such synergistic use of variable air composition from an on-board polymer membrane, many emissions problems can be solved effectively. This paper presents an overview of different applications of air separation membranes for diesel and spark-ignition engines. Membrane characteristics and operating requirements are examined for use in automotive engines.

A two-stage Delphi study was conducted to collect information that would enable a technical and economic assessment of electric (EV) and hybrid electric (HEV) vehicles. The first-stage worldwide survey was completed in fall 1994 while the second-stage was completed by summer 1995. The paper reports results from the second round of the survey and the major differences between the two rounds. This second-stage international survey obtained information from 93 expert respondents from the automotive technology field. The second stage response provided the following key results. EVs will penetrate the market first followed by internal combustion engine powered HEVs while gas turbine and fuel cell powered HEVs will not have any significant penetration until after 2020. By 2020 EVs and internal combustion engine powered HEVs are projected to have approximately a 15% share of the new vehicle market.

Analytical studies of oxygen-enriched diesel engine combustion have indicated the various benefits as well as the need for using cheaper fuels with water addition. To verify analytical results, a series of single-cylinder diesel engine tests were conducted to investigate the concepts of oxygen enriched air (OEA) for combustion with water emulsified fuels. Cylinder pressure traces were obtained for inlet oxygen levels of 21% to 35% and fuel emulsions with water contents of 0% to 20%. Data for emulsified fuels included no. 2 and no. 4 diesel fuels. The excess oxygen for the tests was supplied from compressed bottled oxygen connected to the intake manifold. The cylinder pressure data was collected with an AVL pressure transducer and a personal computer-based data logging system. The crank angle was measured with an optical encoder. In each data run, 30 consecutive cycles were recorded and later averaged for analysis.